Application of Solar UV Radiation in the Photo-Fenton Process for Coffee Agroindustry Wastewater Treatment

Authors

  • Elida Novita Program Study of Agricultural Engineering, Faculty of Agricultural Technology, University of Jember, Jember, Indonesia. https://orcid.org/0000-0001-5210-4694
  • Sandi Ragil Kurnia Putra Program Study of Agricultural Engineering, Faculty of Agricultural Technology, University of Jember, Jember, Indonesia. https://orcid.org/0009-0003-0747-0961
  • Hendra Andiananta Pradana Program Study of Food Crop Production, Department of Agricultural, Polytechnic of Banyuwangi, Banyuwangi, East Java, Indonesia. https://orcid.org/0000-0001-9249-4121
  • Asmak Afriliana Program Study of Agricultural Product Technology, Faculty of Agricultural Technology, University of Jember, Jember, Indonesia. https://orcid.org/0000-0002-4079-9537
  • Soni Sisbudi Harsono Program Study of Agricultural Engineering, Faculty of Agricultural Technology, University of Jember, Jember, Indonesia. https://orcid.org/0009-0006-2870-2380
  • Bambang Herry Purnomo Program Study of Agro-Industrial Technology, Faculty of Agricultural Technology, University of Jember, Jember, Indonesia. https://orcid.org/0000-0003-0701-2090
  • Tjahjo Tri Hartono Program Study of Environment Science, Faculty of Engineering and Science, University of Ibn Khaldun Bogor, Bogor, Indonesia. https://orcid.org/0000-0002-2154-8716
  • Nurfila Sari Sudirman 1Program Study of Agricultural Engineering, Faculty of Agricultural Technology, University of Jember, Jember, Indonesia. https://orcid.org/0009-0007-5116-1532

DOI:

https://doi.org/10.25186/.v20i.2340

Abstract

Wastewater from coffee agro-industrial activities tends to be brown in colour and rich in organic matter, potentially causing environmental pollution. Biological treatment has not been fully effective in reducing its colour due to the presence of dark pigments. This study aims to development of utilizing ultraviolet light radiation from the sun and comparing its efficiency with ultraviolet light from lamps in purifying coffee processing wastewater. The research stages consisted of photoreactor preparation; preparation of Fenton reagent doses of H₂O₂ and Fe₂(SO₄)₃; ultraviolet radiation; and analysis of the pollution reduction parameters. The results show that the application of ultraviolet radiation from sunlight has a positive impact on the quality of coffee agroindustry wastewater. The recommended treatment combination of Fe₂(SO₄)₃ 0.0015M and H₂O₂ 0.2M is the best alternative for improving its quality which has reduction efficiency (RE) namely 96.27% (TSS), 97.68% (turbidity), 99.98% (colour absorbance), and 95.17% (COD) respectively. The ultraviolet from sunlight application in the photo-Fenton method is more effective and efficient than using light from artificial UV lamps. The results of this experiment offer an alternative tertiary treatment for coffee agroindustry or Small and medium enterprises (SMEs) wastewater that is effective, efficient, low-cost, and relatively easy to implement.

Key words: Advanced oxidation processes (AOPs); coffee wastewater processing; photo-Fenton; solar UV.

Author Biography

Sandi Ragil Kurnia Putra, Program Study of Agricultural Engineering, Faculty of Agricultural Technology, University of Jember, Jember, Indonesia.

21

References

ALI, N. S. et al. Performance of a solar photocatalysis reactor as pretreatment for wastewater via UV, UV/TiO2, and UV/H2O2 to control membrane fouling. Scientific Reports, 12:16782, 2022.

ALITO, O-S.; RANTALAINEN, A-L. Anticancer drugs gemcitabine, letrozole, and tamoxifen in municipal wastewater and their photodegradation in laboratory-scale UV experiments. Water, Air, & Soil Pollution, 233:292, 2022.

BARROS, V. G. et al. Treatment of biodigester coffee processing wastewater using fenton’s oxidation and coagulation/flocculation. Environmental Pollution, 259:113796, 2020.

BIDIRA, F. et al. Phosphate and nitrate removal from coffee processing wastewater using a photoelectrochemical oxidation process. Journal of Environmental and Public Health, 4:4382491, 2022.

BRILLAS, E. Solar photoelectro-Fenton: A very effective and cost-efficient electrochemical advanced oxidation process for the removal of organic pollutants from synthetic and real wastewaters. Chemosphere, 327:138532, 2023.

CAMPOS, R. C. et al. New sustainable perspectives for “coffee wastewater” and other by-products: A critical review. Future Food, 4:100058, 2021.

DADI, D. et al. V-DER. Assessment of the effluent quality of wet coffee processing wastewater and its influence on downstream water quality. Ecohydrology & Hydrobiology, 18:201-211, 2018.

DAS, A.; ADAK, M. K. Photo-catalyst for wastewater treatment: A review of modified Fenton, and their reaction kinetics. Applied Surface Science Advances, 11:100282, 2022.

EL-GAWAD, H. A. et al. Novel collector design and optimized photo-fenton model for sustainable industry textile wastewater treatment. Scientific Reports, 14:8573, 2024.

FENG, J. et al. Coffee melanoidins as emulsion stabilizers. Food Hydrocolloids, 139:108552, 2023.

FIRDISSA, E. et al. Coffee drying and processing method influence quality of arabica coffee varieties (Coffee arabica L.) at Gomma I and Limmu Kossa, Southwest Ethiopia. Journal of Food Quality, Article ID 9184374, 8 pages, 2022.

GKORGKOLIA, C.; FYTIANOS K. Degradation of the endocrine-disrupting compound triadimenol using photo-Fenton reaction system and experimental design. Water, Air, & Soil Pollution, 234:57, 2023.

GOMEZ, C. A. et al. Analysis of the capacity of the Fenton process for the treatment of polluted wastewater from the leather dyeing industry. The Scientific World Journal, 4724606, 21 pages, 2023.

GONZALEZ, Y. et al. UV disinfection system for wastewater treatment: emphasis on reactivation of microorganisms. Sustainability, 15:11262, 2023.

HAILEMARIAM, F. A.; VELMURUGAN, P.; SELVARAJ, S. K. Treatment of wastewater from coffee (Coffea arabica) industries using mixed culture Pseudomonas fluorescens and Escherichia coli bacteria. Materialstoday: Proceedings, 46:7396-7401, 2021.

HAMED, M. A. R. et al. Radiant remedies – maximizing wastewater treatment efficiency with optimized photo-fenton techniques. Journal of Ecological Engineering, 25:324-332, 2024.

IJANU, E. M. et al. Coffee wastewater treatment: A critical review on current treatment technologies with a proposed alternative. Applied Water Science, 11:1-11, 2020.

LANGNER, E.; RZESKI, W. Biological properties of melanoidins: a review. International Journal of Food Properties, 17:344-353, 2014.

LIN HH-H.; LIN AY-C. Solar photo-Fenton oxidation of cytostatic drugs via Fe(III)-EDDS at circumneutral pH in an aqueous environment. Journal of Water Process Engineering, 41:102066, 2021.

MANGKU, I. G. et al. The effects of processing methods on the quality of arabica Kintamani green beans. International Journal of Food Studies, 11(2):374-385, 2022.

MANSOUR, S. A. et al. Photocatalytic performance and photodegradation kinetics of fenton-like process based on haematite nanocrystals for basic dye removal. SN Applied Sciences, 1:265, 2019.

MINISTER OF ENVIRONMENT OF THE REPUBLIC OF INDONESIA. Peraturan Menteri Lingkungan Hidup Republik Indonesia Nomor 5 Tahun 2014. 2014. Available in: https://jdih.maritim.go.id/en/peraturan-menteri-negara-lingkungan-hidup-no-5-tahun-2014. Access in: 9 May 2025.

MONTES, C. A. et al. Vertical flow wetlands as the core for the sustainable treatment of coffee wastewater in small communities in Colombia: preliminary results. Water Science & Technology, 8:1974-1981, 2023.

MOYA-RAMIREZ, I. et al. Spent coffee grounds as feedstock for the production of biosurfactants and the improved recovery of melanoidins. World Journal of Microbiology and Biotechnology, 39:254, 2023.

NAWAZ, S. et al. Ultrasound-assisted hydrogen peroxide and iron sulfate mediated Fenton process as an efficient advanced oxidation process for the removal of Congo red dye. Polish Journal of Environment Studies, 31:2749-2761, 2022.

NOVITA, E. Biodegradability simulation of coffee wastewater using instant coffee. Agriculture and Agricultural Science Procedia, 9:217-229, 2016.

NOVITA, E. et al. Water hyacinth potential in the pollution impact reduction of coffee agroindustry wastewater. Jurnal Riset Teknologi Pencegahan Pencemaran Industri, 14(2):10-22, 2023.

PANDEY, A. K. et al. Utilization of solar energy for wastewater treatment: Challenges and progressive research trends. Journal of Environmental Management, 297:113300, 2021.

PONCET, V. et al. Which diversification trajectories make coffee farming more sustainable?. Current Opinion in Environmental Sustainability, 68:101432, 2024.

PONCE-ROBLES, L. et al. Integrated full-scale solar CPC/UV-LED–filtration system as a tertiary treatment in a conventional WWTP for agricultural reuse purposes. Photochemical & Photobiological Sciences, 22:641-654, 2023.

ROKHMAN, D. N. et al. Sustainable specialty coffee production: An agronomy perspective (A review). IOP Conference Series: Earth and Environmental Science, 1230:012067, 2023.

SHAH, R. A. R. et al. Prospective plants as biocoagulant-flocculants for removal of total suspended solids in coffee effluent treatment. Chemical Engineering Research and Design, 198:282-295, 2023.

THARASAWATPIPAT, C. et al. Evaluation of wastewater treatment and solar energy-based solutions for enhanced water quality improvement. Journal of Ecological Engineering, 26:198-208, 2025.

VELEGRAKI, T.; MANTZAVINOS, D. Solar photo-Fenton treatment of winery effluents in a pilot photocatalytic reactor. Catalysis Today, Part A:153-159, 2015.

WANG, N. et al. A review on Fenton-like processes for organic wastewater treatment. Journal of Environmental Chemical Engineering, 4(1):762-787, 2016.

WANG, Q. et al. Molecular mechanisms of interaction between enzymes and Maillard reaction products formed from thermal hydrolysis pretreatment of waste activated sludge. Water Research, 206:117777, 2021.

WANZALA, R. W.; MARWA, N. L.; WANGA, E. N. Impact of agricultural credit on coffee productivity in Kenya. World Development Sustainability, 5:100166, 2024.

ZAKARIA, N. et al. Batik effluent treatment and decolorization - a review. Water (MDPI), 15:1339, 2023.

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Published

2025-09-30

How to Cite

NOVITA, Elida; PUTRA, Sandi Ragil Kurnia; PRADANA, Hendra Andiananta; AFRILIANA, Asmak; HARSONO, Soni Sisbudi; PURNOMO, Bambang Herry; HARTONO, Tjahjo Tri; SUDIRMAN, Nurfila Sari. Application of Solar UV Radiation in the Photo-Fenton Process for Coffee Agroindustry Wastewater Treatment. Coffee Science - ISSN 1984-3909, [S. l.], v. 20, p. e202340, 2025. DOI: 10.25186/.v20i.2340. Disponível em: https://coffeescience.ufla.br/index.php/Coffeescience/article/view/2340. Acesso em: 24 jan. 2026.